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Cardiff University Researchers Develop Ground Breaking Gas Conversion Process

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A simple, low-cost method of directly converting natural gas into useful chemicals and fuels has been developed by researchers at Cardiff University.

Experts from Cardiff Catalysis Institute (CCI) used the precious metal gold as a key ingredient, working in collaboration with researchers at Lehigh University, USA and the National Centre for Magnetic Resonance in Wuhan, China.

Whilst natural gas is one of the greenest fossil fuels, it still emits dangerous greenhouse gases into the atmosphere when burned.

This has led researchers to devise novel ways of converting methane, which accounts for 70-90% of natural gas, into more useful products, such as a fuels and chemicals, in a simple, cost-effective and low-carbon manner.

In a study published in Nature Catalysis, the team demonstrated, for the first time, the direct conversion of methane into methanol and acetic acid using a gold catalyst.

Up until now, this has only been achieved through indirect routes which include multiple steps that are highly energy consuming and very costly.

By examining the catalyst using high-powered electron microscopy, it was revealed that the active catalyst did not contain gold atoms or clusters, but rather gold nanoparticles – extremely small particles between 3 to 15 nanometres in size that can exhibit significantly different physical and chemical properties to their larger material counterparts.

The production of methanol using this catalyst was expected; however, the novelty of the new method came in the production of acetic acid. Acetic acid is a common industrial chemical with large quantities used to make products such as ink for textile printing, dyes, photographic chemicals, pesticides, pharmaceuticals, rubber and plastics.

Methanol, meanwhile, is commonly used as a precursor to many other commodity chemicals, as well as a biofuel.

Despite the well-known inertness of the precious metal gold, pioneering research by scientists at the Cardiff Catalysis Institute has demonstrated that it is, in fact, an extremely efficient and reliable catalyst that can be used effectively in many important industrial processes.

Co-author of the study Professor Graham Hutchings, Regius Professor of Chemistry, Cardiff Catalysis Institute, said:

The oxidation of methane, the main component of natural gas, to selectively form oxygenated chemical intermediates using molecular oxygen has been a long-standing grand challenge in catalysis.

CCI’s mission is to improve the understanding of catalysis, develop new catalytic processes with industry, and promote the use of catalysis as a sustainable 21st century technology.

The Institute will move to a bespoke Translational Research Hub

(TRH) later this year. Here, researchers will foster partnerships with national and international enterprises to promote academic-to-business, and business-to-business relationships and fuel economic growth in Wales and beyond.